Tetra-μ-benzoato-bis[(6-methylquinoline)copper(II)]
نویسندگان
چکیده
منابع مشابه
Tetra-μ-benzoato-bis[(quinoxaline)copper(II)]
The paddlewheel-type centrosymmetric dinuclear title complex, [Cu(2)(C(7)H(5)O(2))(4)(C(8)H(6)N(2))(2)], contains four bridging benzoate groups and two terminal quinoxaline ligands. The octa-hedral coordination around each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a quinoxaline mol-ecule [Cu-N = 2.2465 (18) Å] and by the second Cu atom [Cu⋯Cu = 2.668 (5) Å...
متن کاملTetra-μ-benzoato-bis[(3,5-dimethylpyridine)copper(II)]
In the centrosymmetric binuclear title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(7)H(9)N)(2)], the Cu(II) atom is coordinated by four O atoms from benzoate anions and one N atom from a dimethyl-pyridine ligand. A paddle-wheel-like dimer is formed by two Cu(II) ions and four benzoate anions with two 3,5-dimethyl-pyridine ligands at the axial position of the Cu(II) ions. The dihedral angle between the ...
متن کاملTetra-μ-benzoato-bis[(3-methylquinoline)copper(II)](Cu—Cu)
In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex mol-ecule contains four bridging benzoate groups and two terminal 3-methyl-quinoline ligands. The asymmetric unit contains one and a half mol-ecules with a total of three independent Cu atoms; there is an inversion center at the mid-point of the Cu⋯Cu bond in one molecule. The octa-hedral coo...
متن کاملTetra-μ-benzoato-bis[(6-methylquinoline)copper(II)]
In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methyl-quinoline ligands. The asymmetric unit contains one-half of the whole mol-ecule, and there is an inversion center at the mid-point of the Cu⋯Cu bond. The octa-hedral coordination of each Cu atom, with four O atoms in th...
متن کاملTetra-μ-benzoato-κ8 O:O′-bis[(benzoic acid-κO)nickel(II)]
The title compound, [Ni(2)(C(7)H(5)O(2))(4)(C(7)H(6)O(2))(2)], is composed of two Ni(II) ions, four bridging benzoate anions and two η(1)-benzoic acid mol-ecules. The [Ni(2)(PhCOO)(4)] unit adopts a typical paddle-wheel conformation. The center between the two Ni(II) atoms represents a crystallographic center of inversion. In addition, each Ni(II) ion also coordinates to one O atom from a benzo...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808016516